Basic Chemistry Swimming Pool

There are 2 basic elements to pool chemistry: water balance and sanitation.

1. Water Balance

Your pool water is delicate, and in order to reach perfect pool harmony, it must be balanced.

Balancing your pool means keeping the pH of the water between 7.4 and 7.6, which is slightly above neutral on the pH scale.

the-ph-scale-swimming-pool.jpg

There are 3 main ingredients to keeping this balanced: pH, alkalinity and calcium hardness.

pH

Proper pH Level: 7.4 to 7.6

swimming-pool-phpH alone is unstable. Rainwater, swimmers, and just about anything that enters the water can affect the pH level. When pH is low, it means your water is acidic, and when it’s high, you water is basic.

To give you an idea of how pH works, our tears are pH neutral. If they had a low pH, it would burn when we cried. And if the pH was high, it would dry out our eyes.

Always keep a good supply of pH Increaser on hand because this reading can change frequently.

The opposite of pH increaser is pH decreaser. Chances are you’ll use less of this chemicals but it’s still a good idea to keep on hand to help remove stains and clear the water.

Alkalinity

Proper Alkalinity Level: 100 to 150 ppm (parts per million)

swimming-pool-alkalinityAlkalinity is a pH buffer, meaning it helps to keep the pH from drastically moving up and down the pH scale by absorbing major changes to the waters before affecting the pH.

It’s also a good idea to keep a hefty supply of alkalinity increaser on hand since this reading can fluctuate.

Calcium Hardness

Proper Calcium Hardness Level: 200 to 275 ppm (parts per million) for plaster pools.

calcium-hardness-range-swimming-poolWhile calcium hardness is not really part of water balance, it’s still important to talk about. Without calcium, your water will become hungry for it and seek to fulfill it’s appetite by feasting on your pool’s plaster, and anywhere else it can get it.

Adding calcium hardness to your water will help protect your pool walls and equipment in the long run. However, too much calcium can cause scaling and other issues.

NOTE: Calcium hardness should only be added once in the beginning of the season if needed. Keep an eye on it throughout the year to make sure it stays within range. If the calcium in your water is high, you will have to dilute the water by draining it a tad and refill with fresh water.


How To Keep Your Water Balanced

It’s important to keep your eye on your pH and alkalinity levels – at least daily until you’ve gained a sense on how your pool works – by using a home test kit or test strips.

To keep your pool balanced, you need to keep these chemicals on hand:

  • pH Increaser
  • pH Reducer
  • Alkalinity Increaser

You’ll notice I didn’t mention alkalinity decreaser. Most major pool chemical companies do not produce it. If your pH and alkalinity are low, alkalinity increaser will raise both. You may need to add a little pH increaser if the pH doesn’t reach 7.4 – like fine tuning an instrument.

If your pH and alkalinity are both high, pH decreaser will lower both. If just your alkalinity is high, your pH will also be high and you can use pH decreaser.

If your pool is properly balanced at all times, it will make your pool’s sanitizer work more effectively.


2. Sanitation

The most common form of pool sanitizer is chlorine, but there are others you can use, including:

  • Bromine: chlorine’s halogen cousin
  • Biguanide: Baquacil or SoftSwim
  • Minerals: silver and copper

 

Chlorine

Proper Chlorine Level: 3 ppm (parts per million)

chlorine-tablets-swimming-pool.jpgChlorine is an extremely effective bacteria and algae killer, and cost effective.

There are a few ways you can introduce chlorine into the pool water, including:

  • Chlorine tablets
  • Chlorine granular or powdered chlorine
  • Salt Chlorine Generator: turns regular table salt into chlorine

Chlorine tablets are the most popular form. They come in 3” and 1” tablets and can be added to a floating chlorine dispenser, a chlorinator, or the skimmer basket(s) in your pool.

NOTE: When buying chlorine make sure you look for Trichloro or Dichloro as an active ingredient. These types of chlorine products are stabilized. UV rays from the sun eat up chlorine, but if it’s stabilized, it drastically slows down this process. We will talk more about chlorine stabilizer later.

Bromine

Proper Bromine Level: 3 to 5 ppm (parts per million)

bromine-tablets-swimming-poolBromine is chlorine’s halogen cousin and it more commonly used in hot tubs and indoor pools because it doesn’t give off that “chlorine” smell.

Bromine works a little differently than chlorine and it’s not as effective when dealing with certain types of algae. It’s not recommended for outdoor pools in direct sunlight. Sunlight eats up bromine very fast because it’s unstabilized.

Biguanide

Proper Biguanide Level: 30 to 50 ppm (parts per million)

Baquacil-Jug-swimming-poolThis is a chlorine alternative. It’s an effective sanitizer for swimming pools and even makes the water feel smoother.

Sanitizer is part of a total chemical package and should not be mixed with standard pool chemicals. You must stick the pool chemicals offered by these brands, including shock and algaecide.

These chemical packages are more expensive than traditional chlorine-compatible chemicals, and they come in liquid form.

Minerals

 

Proper Chlorine Level: 0.5 ppm (parts per million)

swimming-pool-minerals.jpgSilver and copper minerals are introduced to the water by an mineral system that resembles a chlorinator. These minerals work to sanitize the water, but they are much slower than chlorine.

A mineral system is NOT a complete chlorine alternative as chlorine is still required – but only a small amount as backup.

 


Pool Shock

Pool-Shock-swimming-pool.pngShocking your pool is another term for adding a ton of chlorine to your pool.

When a chlorine particle attacks and kills bacteria, or other organic material in your water, it is read as combined chlorine. This just floats around in your water until it can be oxidized and broken apart.

In order to oxidize, you must “shock” the water by adding enough chlorine – or non-chlorine shock including Potassium Monopersulfate – to reach breakpoint oxidation.

What is Breakpoint Oxidation?

To reach breakpoint oxidation, the chlorine reading must be 10 ppm over your combined chlorine reading.

Your chlorine has two readings: free chlorine (FC) and combined chlorine (CC). Free chlorine refers to the chlorine that is free and available to kill. Combined chlorine is chlorine that has done it’s job.

NOTE: Pool shock products are made with unstabilized chlorine or no chlorine at all. They will go in, do their job, and get eaten up by the sun’s UV rays very fast. That’s why it’s important to shock your pool at night or dusk, and let it work for 8 hours (with the pool running) throughout the night.

You could shock or oxidize your pool at least once a week.


Other Types of Pool Chemicals You Need To Know About

If you only used pH, alkalinity, calcium, and a sanitizer, you could keep a clean and healthy pool all year long. However, there are a few more products you should be familiar with in case you need or decide to use them.

Cyanuric Acid (Water Stabilizer)

Most chlorine products you add to the water will be stabilized chlorine. However, if you start with fresh water, you might want to add some cyanuric acid (aka water stabilizer) as a stabilizer base so that the chlorine doesn’t get burned off by the sun’s UV rays so quickly. This chemical will protect your chlorine from the sun.

Algaecide

Algaecide is a algae preventative. There are certain algaecides on the market that claim to kill algae, but the best killer is chlorine.

Use algaecide as a backup. If your chlorine levels dip down, and you don’t catch it in time, the algaecide will keep the algae at bay until you can get the chlorine back up.

Clarifier and Floc

A water clarifier helps by bringing all those tiny particles that are making your water cloudy and combining them into bigger particles that your filter will have a better chance of filtering out.

Floc or Flocculant, grabs those tiny particles, brings them together, and sinks them to the bottom. With pool floc, you will have to manually get those particles out of your water by vacuuming to waste.

Stain and Scale Remover (Metal Remover)

If you have metals in your water, like copper and iron, you can use a metal remover or stain and scale remover to keep those metals in solution so that your filter can filter them out.

If metals come out of solution that can attach themselves to the walls and other parts of your pool and produce unsightly stains.


To Recap

To maintain a safe and healthy swimming pool, you need to keep your pool chemicals at the following levels:

  • pH: 7.4 to 7.6
  • Alkalinity: 100 to 150 ppm
  • Calcium Hardness: 175 to 225 ppm and 225 to 275 ppm for plaster pools
  • For Chlorine or Salt Water Pools: 1 to 3 ppm (I recommend you keep it at 3 ppm)
  • For Bromine Pools: 3 to 5 ppm
  • For Biguanide Pools: 30 to 50 ppm
  • For Mineral System Pools: 0.5 ppm of chlorine

Make sure to practice good pool circulation and filtering, and keep your pool cleaned by vacuuming and skimming frequently.

Our 3 Cs of pool care include: cleaning, circulation and chemicals. We suggest you read these posts to understand how to keep your pool clean and healthy all season long:

We added The Anatomy of a Swimming Pool because you should know what you’re working with before you get started.

Sources:
https://www.swimuniversity.com/basic-pool-chemistry-101/

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